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Artificial atoms,
also called quantum dots, are actually made of dozens of atoms, but they act
very much just like a single atom in one important respect: when you provide
them with the right amount (quanta) of energy, they will emit light with a
very distinct color. This property makes them useful in applications as diverse
as data communications and medical testing.
To understand how an artificial atom emits light, first
consider how a real atom does it. In a real atom, electrons
surround a dense nucleus and occupy different “energy
levels.” When a particle of light called a photon strikes
the atom, an electron will take that energy to temporarily “leap” to
a higher energy level. When that “excited” electron
comes back “down,” it will release that energy
to emit a new photon with a particular frequency, or color.
Each different kind of atom (i.e. each element in the periodic
table) emits a unique combination of light colors because
of the limited number of ways its electrons can change or
leap from one state to another. The rules of physics at the
size scale of atoms, called quantum mechanics, are what account
for these rules or limitations.
When we combine dozens of atoms to make a quantum dot, it
is still small enough for these quantum rules to hold. In
my lab, we typically make quantum dots out of semiconducting
elements, such as silicon or even molecules such as indium
arsenide. When we illuminate a quantum dot with the right
amount of energy, just like an atom it will absorb that energy
and then emit photons of only particular wavelengths. The
wavelengths are determined by the size of the dot, which
depends on the number of atoms that compose the dot. By controlling
the number of atoms in the dots, we are producing an “artificial
periodic table,” in which the energy levels of the
atoms determines how the electrons are arranged and therefore
how they can leap between levels in our artificial atom.
So what good are artificial atoms? In my research we use
them to create lasers or to amplify light. We can make quantum
dots that emit desired colors of light when they are exposed
to electrical currents in a process is similar to that at
play in an LED. The current is a flow of negatively charged
electrons going one way and holes (gaps in a material where
electrons should be, but aren’t) flowing the opposite
direction. When the electrons meet the holes, they give off
a photon. Properly added to a material, quantum dots can
make this happen efficiently, because they can concentrate
the flow of electrons and holes much like the drain in a
shower. We’ve been able to make artificial atom lasers
and amplifiers to improve how we use light in data communications
and computer chips.
Other researchers use quantum dots in medical testing. Let’s
say you wanted to see whether five particular genes were
present in somebody’s DNA. One way is to create five “tags” that
will link up just to those five genes. When the tags are
exposed to special lights, those tags will then shine if
they’ve found and linked to their targets. The trick
has been to make good tags. Traditionally, people have used
molecules that light up, but each kind of molecule needs
to be exposed to its own color of light to work. That’s
difficult to arrange because the molecules emit over a wide
range of colors that begin to overlap with each other.
Quantum dots, by design, can all be stimulated by the same
color of light, however, the colors they subsequently emit
don’t overlap. So with just one light source, you can
see exactly the colors you expect if the tags have found
their gene targets.
We still have a lot to learn about quantum dots, the key
challenges today are making them precisely the size we want
and placing them exactly where we want them in electronic
and photonic devices. We’d like better control of where
they end up.
Despite the challenges, quantum dots are proving useful
as engineering research tools and are making their way into
commercial use. Their structure is artificial, but their
value is real.
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